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L'énergie libre de Gibbs associée à une transformation physico-chimique à température et pression constantes peut augmenter (ΔG1 > 0) à condition que cette transformation soit couplée à une autre transformation physico-chimique dont la variation d'énergie libre de Gibbs ΔG2 diminue telle que ΔG2 ≤ -ΔG1

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